在过渡金属元素催化下,芳基硼酸与芳基卤化物发生交叉偶联获得联芳基化合物的反应被称为铃木-宫浦偶联反应,实用性非常高,是近年应用最广泛的有机合成反应之一。
本产品以1,8-二氨基萘保护一烃基硼酸,可应用于Oligoarenes的合成。若用酸溶液处理,可较为容易地脱去1,8-二氨基萘保护。

o-Bromophenylboronic Acid
1,8-Diaminonaphthalene, Protected

p-Benzenediboronic Acid Pinacol Ester,
1,8-Diaminonaphthalene, Protected

◇ 用酸溶液处理,一烃基硼酸(Boronic acid)容易脱保护
◇ 可用于Oligoarenes的合成

Synthesis of polyboronyl-substituted oligoarenes using diboronyl coupling module

[参考文献]

Noguchi H., Shioda T., Chou C.-M. and Suginome M.:Org. Lett., 10, 377(2008).
Noguchi H., Hoji K. and Suginome M.:J. Am. Chem. Soc., 129, 758(2007)

[反应例]

3-(2-Bromopyridine)boronic Acid
1,8-Diaminonaphthalene, Protected

[-]
029-16861 (1 g) JPY 13,000
025-16863 (5 g) JPY 46,000

5-(2-Bromopyridine)boronic Acid
1,8-Diaminonaphthalene, Protected

[-]
026-16871 (1 g) JPY 11,000
022-16873 (5 g) JPY 39,000

m-Aminophenylboronic Acid
1,8-Diaminonaphthalene, Protected

[-]
016-23421 (1 g) JPY 12,000
012-23423 (5 g) JPY 42,000

o-Bromophenylboronic Acid
1,8-Diaminonaphthalene, Protected

[927384-42-7]
026-16631 (1 g) JPY 11,000
022-16633 (5 g) JPY 39,000

m-Bromophenylboronic Acid
1,8-Diaminonaphthalene, Protected

[927384-43-8]
023-16641 (1 g) JPY 11,000
029-16643 (5 g) JPY 39,000

p-Bromophenylboronic Acid
1,8-Diaminonaphthalene, Protected

[927384-44-9]
020-16651 (1 g) JPY 11,000
026-16653 (5 g) JPY 39,000

o-Benzenediboronic Acid Pinacol Ester,
1,8-Diaminonaphthalene, Protected

[950511-18-9]
021-16701 (1 g) JPY 15,000
027-16703 (5 g) JPY 60,000

m-Benzenediboronic Acid Pinacol Ester,
1,8-Diaminonaphthalene, Protected

[950511-17-8]
028-16711 (1 g) JPY 15,000
024-16713 (5 g) JPY 60,000

p-Benzenediboronic Acid Pinacol Ester,
1,8-Diaminonaphthalene, Protected

[950511-16-7]
025-16721 (1 g) JPY 15,000
021-16723 (5 g) JPY 60,000

正文中列出的所有试剂只能用于测试或研究,不能作为"药品","食品","家庭用品"等使用。